Electric Charge and Coulomb's Law
From MyMCAT
Contents |
Introduction
Probably everyone is familiar with the concept of electric charges. Static shocks, lightning, and batteries all have to do with charge. But how do you quantify charge? What does having something with charge mean and what can it do?
Charge
To define charge more formally, we must understand a few basic concepts of charge:
- There are two kinds of charge, positive and negative. (Protons carry positive charge, while electrons carry negative charge.)
- Like charges repel, unlike charges attract. (Electrons go towards protons.)
- Positive overall charge implies there are more protons than electrons in a molecule, while negative charge implies the reverse.
- Charge is quantized. All values of charge come in multiples of the elementary charge e. Electrons have a charge of -e, while protons have a charge of +e.
Charge is generally given the symbol q, but because the charge of an electron is a rather small number, it is more often measured measured in Coulombs (C), where e = 1.60 x 10-19Coulombs. As an example, a Ca2+ ion would have a charge of 2e, or 3.20 x 10-19 Coulombs.
The Law of Conservation of Charge
The Law of conservation of charge states that the net charge of an isolated system remains constant.
If a system starts out with an equal number of positive and negative charges, there's nothing we can do to create an excess of one kind of charge in that system unless we bring in charge from outside the system (or remove some charge from the system). Likewise, if something starts out with a certain net charge, say +100 e, it will always have +100 e unless it is allowed to interact with something external to it.
Conductors versus Insulators
Most things are electrically neutral; they have equal amounts of positive and negative charge. Metals are good conductors of electric charge, while plastics, wood, and rubber are not. They're called insulators. Charge does not flow well through insulators, which is why wires you plug into a wall socket are covered with a protective rubber coating. Charge flows along the wire, but not through the plastic coating to you.
Most materials are either conductors or insulators. The difference between them is that in conductors, the outermost electrons in the atoms are so loosely bound to their atoms that they're free to travel around. In insulators, on the other hand, the electrons are much more tightly bound to the atoms, and are not free to flow. Semi-conductors are a very useful intermediate class, not as conductive as metals but considerably more conductive than insulators. By adding impurities to semi-conductors the conductivity can be specifically controlled. (It is this process that make modern day electronics possible!)
Coulomb's Law
We have mentioned that charges attract and repeal each other, but so far have provided a method for determining by how much or how strong this attraction/repulsion is. Coulomb's law provides the empirical calculations necessary to determine this. To calculate the force exerted by one charge, q1 on another charge q2 we use the equation

where r is the distance between the charges and k is the electrostatic constant (related to the electric constant) and is equal to 8.99 x 109NC2m-2.
This formula says that the magnitude of the force is directly proportional to the magnitude of the charges of each object and inversely proportional to the square of the distance between them. When dealing with just two charges, the direction of the force is always either directly towards or against the other charge (depending on if they are attracting or repealing each other).
This force is a vector, so when more than one charge exerts a force on another charge, the net force on that charge is the vector sum of the individual forces. Remember, too, that charges of the same sign exert repulsive forces on one another, while charges of opposite sign attract. This can be determined by the sign of F. F is positive when either two positive values or two negative values for q and Q were used and thus it is a repulsive force. F is negative when two values of opposite sign are used, in which case, F is an attractive force.

